A comparison of spin relaxation and local motion between symmetrically and asymmetrically ring-substituted bisphenol units in dissolved polycarbonates

Carbon-13 and proton spin-lattice relaxation times were measured at two field strengths on solutions 10% by weight of two polycarbonates in C₂D₂Cl₄ from ?20 to +120°C. The first polycarbonate is an asymmetrically substituted form with one chlorine on one of the two phenylene aromatic rings of the bisphenol unit, whereas the second polycarbonate is symmetrically substituted with two chlorines on each of the two rings. The nuclear spin relaxation data are interpreted in terms of several local motions likely in these polymers. Segmental motion was described by the Hall–Helfand correlation function. Segmental motion in the monosubstituted polycarbonate is somewhat slower than in unsubstituted polycarbonate, whereas segmental motion in the tetrasubstituted polycarbonate is considerably slower. Phenylene ring rotation is observed in unsubstituted polycarbonate and in the monosubstituted polycarbonate above 40°C. Below 40°C in the monosubstituted species, and at all temperatures in the tetrasubstituted species, ring rotation is replaced by ring libration as the predominant motion contributing to spin lattice relaxation. In addition, the rotational motion of the two types of rings in the asymmetric monosubstituted form are very similar although not identical. The substituted ring is slightly less mobile than the rings of unsubstituted polycarbonate. This indicates a strong coupling of ring motion, although the coupling leads to less than synchronous motion. Methyl group rotation is present in both polymers and is little affected by the various structural modifications.     

Bi3+和Eu3+在Ca2SiO4中的发光和能量传递

用高温固态反应合成了Ca2SiO4:Bi3+,Ca2SiO4:Eu3+和Ca2SiO4:Eu3+,Bi3+发光体。讨论了不同掺杂量和掺杂种类时Bi3+对Eu3+的5D0-7F1,5D0-7F2发射的影响规律。实验发现,Ca2SiO4:Bi3+在紫外线激发下发出明亮的蓝色光,Ca2SiO4:Eu3+,Bi3+中的Bi3+能将激发能传递给Eu3+,使Eu3+的5D0-7F1和5D0-7F2两种跃迁都大大加强,同时,Bi3+也发出鲜艳的紫色光。     

FULL DISCRETE NONLINEAR GALERKIN METHOD FOR THE NAVIER-STOKES EQUATIONS

This paper deals with the inertial manifold and the approximate inertial manifold concepts of the Navier-Stokes equations with nonhomogeneous boundary conditions and inertial algorithm. Furtheremore, we provide the error estimates of the approximate solutions of the Navier-Stokes Equations.     

激光二极管泵浦单频连续工作的Nd：YAG激光器

在国内首次报道了激光二极管泵浦单频连续工作的Ｎｄ：ＹＡＧ激光器，采用扭摆模腔技术方法，在８０８ｎｍ激光二极管连续泵浦下，取得１０６４ｎｍ连续单频工作，输出功率５５ｍＷ的结果，泵浦阈值２７６ｍＷ，斜率效率２３％，线宽小于２５ＭＨｚ（受仪器测量精度限制）。     

一些高Tc超导体的弹性性质

 本文用超声相比较方法测定了高T_c超导体La_1.85Sr_0.15CuO₄，La₂CuO₄和YBa₂Cu₃O₇的纵波和横波声速，进而导出了它们的纵向模量、切变模量、杨氏模量、泊松比、德拜温度及定体比热。在La_1.85Sr_0.15CuO₄样品上，还进行了压力实验，发现所有弹性模量都是随压强增加而增加。定体比热c_V和泊松比σ在高压下则略有下降。德拜温度是随压强增加而增加的。     

F－L模型的状态方程与退禁闭相变图象

用温度场论方法计算了Ｆ－Ｌ模型在有限温度和密度下的状态方程，分析了压强对净重子数密度的等温线．结果表明，在平均场近似下，Ｆ－Ｌ模型所给出的退禁闭相变为一级相变．     

氢化丁苯共聚物结构的核磁共振波谱表征Ⅰ.13C谱带的归属

本文分别用JEOL FX-90Q和Bruker AM-300波谱仪测定了氢化聚丁二烯和氢化丁苯共聚物的¹H,¹³C-NMR谱,得到了分辨率较高的谱图和新的结构信息。借助DEPT技术确定了各谱带的CH或CH₂类型。利用Grant-Paul和Lindeman-Adams介绍的化学位移经验计算公式,考虑苯基对α、β和γ碳原子的影响,计算了各种三单元序列中有关碳原子的化学位移。对脂肪碳部分的28组谱带重新进行了归属。化学位移计算值与实测值基本相符,并得到了不同组成的模型聚合物¹³C-NMR谱的各谱带强度变化规律的验证。     

一种实现光源与光纤耦合的方法

本文介绍了一种用显微镜筒与透镜构成的光学系统来实现光源与光纤耦合的方法。该方法具有光路系统小巧方便、耐用、耦合效率高等优点。     

工业CT图像均匀性校正

在工业CT图像重建过程中,射束硬化使得图像出现“杯状”伪影,阵列探测器响应不一致使得图像出现环状伪影、带状伪影和点伪影,影响图像均匀性.本文分析了射束硬化的原理和探测器响应不一致的数学模型,并通过实验,对探测器响应进行多挡板定标得到校正系数表.利用查表插值的方法对投影数据进行均匀性校正,消除上述伪影.     

自体静脉移植血管的拉伸实验研究

本文考察了自体移植静脉的纵向应力应变关系。将狗股静脉移植于股动脉，在术后不同时间切取移植静脉进行纵向单轴拉伸实验。结果表明，移植静脉的应力－应变曲线比正常静脉靠近应力坐标轴并在术后逐渐向左移动。这显示了移植血管管壁组织在术后的逐渐硬化。